explain what is meant by a primary, secondary, tertiary or quaternary carbon atom. A tertiary (3o) carbocation, on the other hand, is one in which three carbons are attached to the carbon with the positive charge. What does that mean? A secondary alcohol is a compound with ahydroxy group. It has been discussed in section 9.3 that different radicals (primary, secondary or tertiary) have different stability and reactivity. For methyl and ethyl alkyl groups there is only one possible connection point so connection prefixes are not necessary. Tertiary is a hydrogen bond between a carbon and THREE other carbons. alkyl group methyl group isopropyl group sec -butyl group isobutyl group Is the mastoid procedure, Really (TV channel) Really Freeview Channel 17 Satellite Freesat Channel 160 Sky (UK) Channel 142 What channel is itv1 plus 1 on Sky? represent the various types of organic compounds using the symbol "R" to represent any alkyl group. A tertiary carbon (#3 with a degree symbol) is a carbon that is attached to three other carbons. Alkanes can be described by the general formula CnH2n+2. The symbol R is used to designate a generic (unspecified) alkyl group. This will only occur when the hydroxyl group is at the . Tertiary amines lack intermolecular interaction because there is no hydrogen atom available for hydrogen bond formation. Figure \(\PageIndex{1}\): Secondary structure: The -helix and -pleated sheet form because of hydrogen bonding between carbonyl and amino groups in the peptide backbone. The halogen is shown as bonded to the connection point of the alkyl group. A convenient way of memorizing this classification scheme is to remember that a primary carbon atom is attached directly to only one other carbon atom, a secondary carbon atom is attached directly to two carbon atoms, and so on. As a result, we can apply the same principle to hydrocarbons: primary = a hydrogen on a carbon that is attached to only one other carbon. A secondary alcohol has the formula CHROH while a tertiary alcohol has the formula CR2OH, where R indicates a carbon-containing group. The hydrogen which is attached to these carbon atoms is called primary hydrogen. Starting with propyl alkyl groups there is the possibility of a connection other than the very end. Sort by: Top Voted Lexie VanDall 7 years ago When talking about the interactions at the secondary level, ( 5:10 The figure below use the group "R" to represent an alkyl group of unspecified length. There are other variants on the names, but this is the commonest and simplest way of naming these small secondary amines. In a tertiary amine, all of the hydrogens in an ammonia molecule have been replaced by hydrocarbon groups. Where is the mastoid process palpated externally. After completing this section, you should be able to. The most common forms of secondary structure are the -helix and -pleated sheet structures and they play an important structural role in most globular and fibrous proteins. explain what is meant by a primary, secondary, tertiary or quaternary carbon atom. Take a look at the following examples. Dr. Dietmar Kennepohl FCIC (Professor of Chemistry, Athabasca University), Prof. Steven Farmer (Sonoma State University), William Reusch, Professor Emeritus (Michigan State U. Step #1: Pick a carbon Step #2: Count how many carbons are directly attached to it. OK. Beta pleated sheets and alpha helices. In isobutane there are 9 primary hydrogens and only 1 tertiary hydrogen. That means that the formula of the primary amine will be RNH 2 where "R" is an alkyl group. eg: see also primary hydrogen, secondary hydrogen It is helpful to understand the nature and function of each level of protein structure in order to fully understand how a protein works. The differences among primary, secondary, tertiary and quaternary carbon atoms are explained in the following discussion. Tertiary amines. What is the chemical formula for calcium hydrogen sulfate? Determine whether the carbons indicated in the structure below are 1o, 2o, 3o, or 4o. The relative reaction rate of alkyl radicals for chlorination has been measured and has the approximate values of: Figure 9.4b Relative reaction rate of alkyl radicals for chlorination represent the various types of organic compounds using the symbol R to represent any alkyl group. Secondary = a carbon with only TWO other carbons attached to hydrogen. Legal. The first carbon atom that attaches to a functional group, such as a carbonyl, is known as the alpha carbon (C) in organic molecules. Ethanol and butanol are two examples of primary alcohols. The differences among primary, secondary, tertiary and quaternary carbon atoms are explained in the following discussion. In primary amines, only one of the hydrogen atoms in the ammonia molecule has been replaced. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. In chemistry, what is primary secondary and tertiary education? This allows for an easy description of branching in alkanes. . 3.3: Alkyl Groups is shared under a CC BY-SA 4.0 license and was authored, remixed, and/or curated by Steven Farmer, Dietmar Kennepohl, Zachary Sharrett, Krista Cunningham, Tim Soderberg, William Reusch, & William Reusch. Primary amines In primary amines, only one of the hydrogen atoms in the ammonia molecule has been replaced. The simplest level of protein structure, primary structure, is simply the sequence of amino acids in a polypeptide chain. So follow the next rule for hydrogens: Primary hydrogen atoms are attached to primary carbon atoms; We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. alkyl group methyl group primary carbon quaternary carbon secondary carbon Secondary alcohols. . Please indicate the total number of each type 1o, 2o, 3o, and 4o carbons in the following molecule. Secondary structure is determined by Hydrogen bonds between the backbone of the chain. A primary alcohol is an alcohol with a primary carbon atom and a hydroxyl group. I learned in organic chemistry that secondary/tertiary carbanions are less stable than primary carbanions and therefore primary hydrogens are MORE acidic than secondary/tertiary hydrogens. A protein's primary structure is defined as the amino acid sequence of its polypeptide chain; secondary structure is the local spatial arrangement of a polypeptide's backbone (main chain) atoms; tertiary structure refers to the three-dimensional structure of an entire polypeptide chain; and quaternary structure is the . Chemistry Chemistry questions and answers 1- Which of the following compounds has primary, secondary and tertiary hydrogen atoms? Examples include: Naming amines can be quite confusing because there are so many variations on the names. Primary Structure There are 20 different standard L--amino acids used by cells for protein construction. The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. Please indicate the the number of 1o, 2o, and 3o, hydrogens are in the following molecule: Determine whether the Hs indicated in the following structure are 1o, 2o, or 3o. Intermolecular forces in hydrogen sulfide? In Isopentane, the total number of secondary carbon atoms is 1. The removal of this hydrogen results in a stem change from -ane to -yl. In anorganic species, a primary (1) hydrogen is an ahydrogen atom that lives on a primary carbon. don't count. A primary alcohol is one in which the hydroxyl group (-OH) is attached to a carbon atom with at least two hydrogen atoms. )%2F03%253A_Organic_Compounds-_Alkanes_and_Their_Stereochemistry%2F3.03%253A_Alkyl_Groups, \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}}}\) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash{#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)\(\newcommand{\AA}{\unicode[.8,0]{x212B}}\). In organic chemistry, what is a primary hydrogen? There are 8 primary (1o) Cs, 7 secondary (2o) Cs, 2 tertiary (3o) Cs and 2 quaternary (4o) Cs in the structure (seen color coded below). In anorganic species, a tertiary (3) hydrogen is an ahydrogen atom that lives on a tertiary carbon. recognize and name any alkyl group that can be considered to have been formed by the removal of a terminal hydrogen atom from a straight-chain alkane containing ten or fewer carbon atoms. See, for example, primary and secondary hydrogen. Primary carbon is those carbon in which the carbon atoms are attached to one other carbon atom. Accessibility StatementFor more information contact us atinfo@libretexts.org. Normal Pentane has two primary and three secondary atoms, but Isopentane has one secondary and one Tertiary atom. Why do carbon and hydrogen have the same electronegativity? It seems that the more substituted alpha carbon is more acidic than the nearby primary carbon. This video shows you how to identify methyl, primary, secondary, and tertiary hydrogen atoms. explain what is meant by a primary, secondary, tertiary or quaternary carbon atom. Just as there are primary, secondary, and tertiary alcohols, there are primary, secondary, and tertiary amines. H3C CH3 CH3 CH3 faff C-CH- H H CH H3C CH3. This prefix is not commonly used to just indicate alkyl subsistent as discussed above. But what about the hydrogen atoms which are bonded to these carbon atoms? Please indicate the the number of 1o, 2o, 3o, and 4o carbons in the following molecule: Hydrogen atoms are also classified in this manner. These prefixes are often abbreviated with a letter which is italicized. see also primary hydrogen, secondary hydrogen. (The insulin molecule shown here is cow insulin, although its structure is similar to that of human insulin.) Examples of some common alkyl groups are given in the following table. Secondary C-H Bonds Are Weaker Than Primary C-H Bonds, And Result In More Stable Free Radicals How To Quantify "Selectivity" In Free-Radical Chlorination Proteins are macromolecules and have four different levels of structure - primary, secondary, tertiary and quaternary. Is there also a Home Depot screen replacement?, Meant is spelled m-e-a-n-t in the English language. The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. These alkyl groups get the prefix "t.". However it is sometime used to indicate the connection of a functional group onto a straight alkane. The naming system described above is often used to describe halogens which contain only a few carbons. A convenient way of memorizing this classification scheme is to remember that a primary carbon atom is attached directly to only one other carbon atom, a secondary carbon atom is attached directly to two carbon atoms, and so on. Science Chemistry Chemistry questions and answers Question 28 Which of the following compounds has primary, secondary, and tertiary hydrogen atoms? Primary alcohols. Just behind the ears, the mastoid process can be easily discernible. Yes, they can also be primary, secondary, and tertiary. After completing this section, you should be able to. Starting with a three carbon alkyl group (propyl) the possibility of multiple connection points necessitates connection prefixes. Key Terms Make certain that you can define, and use in context, the key terms below. The IUPAC system requires first that we have names for simple unbranched chains, as noted above, and second that we have names for simple alkyl groups that may be attached to the chains. Cycloalkanes are given the same chemical formula as normal alkane counterparts with the same carbon count: cyclopropane, cyclobutane, cyclopentane, cyclohexane, and so on. Other elements such as hydrogen, nitrogen, oxygen etc. In anorganic species, a tertiary (3) hydrogen is an ahydrogen atom that lives on a tertiary carbon. Explanations:- The hydrogen is bonded to a carbon by 1 degree, and when this carbon is bonded to another carbon, the hydrogen is bonded to the primary carbon. Carbons have a special terminology to describe how many other carbons they are attached to. This is not used for pentyl or hexyl groups because there is more than one structure that are not identical that could be named as sec-pentyl or sec-hexyl. This classification only applies to saturated carbons. Note that the "ane" suffix is replaced by "yl" in naming groups. This page titled Tertiary Hydrogen is shared under a All Rights Reserved (used with permission) license and was authored, remixed, and/or curated by Gamini Gunawardena via source content that was edited to the style and standards of the LibreTexts platform; a detailed edit history is available upon request. a)2 b)3 c)4 d)5 This problem has been solved! Also, we will find that the number of carbons attached to a given atom will have subtle effects on its chemistry. Meant is the verb means past tense and participle. 3.3: Alkyl Groups is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by LibreTexts. But lets take 3-methyl-2-butanone as an example. You will find that hydrogen atoms are also classified in this manner. Example - keratin (present in hair, wool, and silk) and myosin (present in muscles), etc. The question then becomes, To what extent is hydrogen? Answer:- Three degree hydrogens are three, two degree hydrogens are five, and three degree hydrogens are zero. What is a tertiary hydrogen, on the other hand? It depends on the carbon atoms they are attached to. Starting with four carbon alkyl groups, there is an isomer which can have a connection to a tertiary carbon. 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MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "Anti-Markovnikov_Addition" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Antiaromatic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Antiaromatic_Annulene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Antiaromatic_Compound : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Anticoplanar : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Antiparallel : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Antiperiplanar : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Anti_Addition : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Anti_Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aprotic_Solvent : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Arene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Arenesulfonic_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Arenium_Ion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aromatic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aromatic_Amine : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aromatic_Annulene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aromatic_Compound : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aromatic_Ether : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aromatic_Hydrocarbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aromatic_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aryl_Carbanion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aryl_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aryl_Ester : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aryl_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aryl_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aryl_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Aryne : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Assisted_Homolysis : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Asymmetric_Carbon_Atom : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Autoxidation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Axial_Bond : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", A_Value : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "Baeyer-Villiger_Oxidation" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Base : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Base_Peak : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Base_Strength : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Beckmann_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "Beer-Lambert_Law" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Benzene_Ring : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Benzilic_Acid_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Benzylic_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Benzylic_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Benzylic_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Benzylic_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Benzyl_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Benzyl_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Benzyne : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Benzyne_Mechanism : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Betaine : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Beta_Amino_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Beta_Anomer : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Beta_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Beta_Cleavage : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Beta_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Bicycloalkane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Birch_Reduction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Boat_Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Bond_Angle : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Bond_Axis : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Bond_Dissociation_Energy : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Branched_Alkane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Bridge : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Bridged_Bicycloalkane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Bridgehead_Carbon_Atom : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "Brnsted-Lowry_Theory" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Bromohydrin : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "C-Terminal" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "Cahn-Ingold-Prelog_Convention" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carbanion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carbanion_Equivalent : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carbene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carbene_Equivalent : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carbenoid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carbocation_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carbocycle : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carbohydrate : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carbonyl_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carbonyl_Compound : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carbonyl_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carbonyl_Oxygen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carboxylate_Ion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carboxylation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carboxylic_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carboxylic_Acid_Anhydride : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carboxylic_Acid_Derivative : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carboxylic_Acid_Ester : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carboxylic_Acid_Ester_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carboxylic_Acid_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Carboxylic_Acid_Salt : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Catalytic_Hydrogenation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Catalytic_Reduction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Center_of_Chirality : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", CFB : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chair_Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chemically_Equivalent_Ligands : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chemical_Ionization : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chemical_Shift : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chemoselective : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chirality_Center : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chiral_Atom : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chiral_Center : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chiral_Molecule : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chlorofluorocarbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chlorohydrin : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chromate_Ester : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Chromic_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", CIP_Convention : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "Cis-Trans_Isomers" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Claisen_Condensation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Claisen_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Clemmensen_Reduction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Combustion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Concerted_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Condensation_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Configuration : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Conformer : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Conjugated_Diene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Conjugated_Double_Bond : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Conjugate_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Conjugate_Addition : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Conjugate_Base : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Constitutionally_Heterotopic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Constitutional_Isomers : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Coordination_Number : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Cope_Elimination : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Cope_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Cope_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Coupling : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Coupling_Constant : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Coupling_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Crossed_Aldol_Condensation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Crossed_Aldol_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Crossed_Claisen_Condensation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Crosslink : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Crown_Ether : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Cumulene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Curved_Arrow : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", Cyanohydrin : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.